Tiffani visits Jake & The Neverland Pirates (October 3, 2012)

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LOS ANGELES, Calif. — Once you have kids in Hollywood, it's usually inevitable that at some point you will voice an animated character to show off to your children.

Tiffani Thiessen is no exception!

The "White Collar" star and mom to two-and-a-half-year-old daughter Harper is following in the footsteps of her former "Beverly Hills, 90210" co-star Tori Spelling and lending her voice to Disney Junior's popular animated series "Jake and the Neverland Pirates."

Access Hollywood has your exclusive first look photo of Tiffani guest-starring as Misty the Wonderful Witch in the new Halloween episode premiering Friday, October 5. She appears alongside Tori, who voices the recurring role of the Pirate Princess. This will be Tiffani's first appearance and, like Tori, the role will be recurring.

"I love doing [voice over] work," Tiffani told Access Hollywood. "It's so much fun to create a different kind of character with just your voice, and then to see how they visually create the character with your voice. It is fun to see."

Tiffani admits her daughter is also a "Mickey Mouse Clubhouse" fan and wonders whether or not Harper will even react to hearing her mom on "Jake."

"I will be curious to see if she will recognize my voice," she added. "She usually sees me on TV and always calls out, "'Mommy on TV!'"

Watching this Halloween-themed episode will be a great kickoff to the upcoming holiday and Tiffani says she and husband Brady Smith have big plans.

"We are all dressing up as a family this year which will be fun. A lot of pictures will be taken for sure!" she revealed.